Microsoft’s App-V Client 5.0 can be deployed with SCCM 2012 quite easily, but there are some prerequisites that need to be installed prior to the client.
| .NET Framework 4.0 # – http://www.microsoft.com/en-gb/download/details.aspx?id=17718Windows Management Framework 3.0 – http://www.microsoft.com/en-gb/download/details.aspx?id=34595
Microsoft Security Advisory: Insecure library loading could allow remote code execution – http://support.microsoft.com/kb/2533623 |
Installation Switches for Pre-Reqs and Client
Install .Net Framework 4.0
Install using the following syntax
dotNetFx40_Full_x86_x64.exe /q /log %temp%\Net4Install.log
Install Windows Management Framework 3.0
Install using the following syntax
wusa.exe Windows6.1-KB2506143-x64.msu /quiet /norestart
Install the Hotfix KB2533623
Install using the following syntax
wusa.exe Windows6.1-KB2533623-x64.msu /quiet /norestart
Install the App-V 5 SP1 Client
Install using the following syntax
appv_client_setup.exe /q /norestart /ACCEPTEULA /log %temp%\App-V5.log
SCCMentor - Paul Winstanley 
These article is more helpful, shows you how to actually setup the apps in SCCM. http://blogs.technet.com/b/configmgr_geek_speak/archive/2013/04/23/getting-started-with-app-v-5-0-using-configuration-manager-2012.aspx
Cheers for link Levi. My article wasn’t intended as a step by step guide. Just the commands needed to deploy. Thanks Paul.