If you read the original post https://sccmentor.wordpress.com/2013/10/17/unable-to-unpublish-app-v-5-apps-with-appdata-redirected/ you’ll note that SCCM 2012 is not able to unpublish applications when you redirect AppData using folder redirection. Well the
Tag: SP2
Unable to unpublish App-V 5 packages with AppData redirected
SCCM 2012 is unable to unpublish applications successfully when folder redirection of the AppData folder is enabled. The appenforce.log file will display the following error